Why is initial cooling of Cryogenic tanks required prior to loading ?
For instance liquefied natural gas (LNG) compresses to a small fraction of its original volume (approximately 1/600) under liquefaction. With the amount of flammable material that LNG contains, it has the potential to be extremely dangerous, if handled improperly. Preparation for loading flammable gasses in ISO Cryogenic tank containers (initial Cool down) of ISO Cryogenic tank containers need extreme caution.
ISO Cryogenic tank containers are designed to withstand a certain service temperature; if this is below ambient temperature the system has to be cooled down to the temperature of the load before transfer. For LNG and ethylene the stress and thermal shock caused by an over-rapid cooldown of the system could cause brittle fracture. Bofort ensures that cooldown operations are carried out carefully in accordance with manuafacturers instructions and with expertise.
Cool down is an operation to pre-cool cryogenic tank containers and lines required before taking on cryogenic flammable gasses. ISO Cryogenic tank containers cool down is carried out by spraying LIN through the spray nozzles of each tank, as LIN received from the shore terminal. The cool down operation from an ambient temperature to a planned temperature, is called ‘initial cool down’ and is to be differentiated from an ordinary cool down operation carried out during transit.
Before a flammable gas can be introduced into a Cryogenic tank containers,the tanks have to be cooled down to a temperature close to that of the gas which is to be loaded. The reasons for this are as follows:
If a cryogenic gas is introduced directly into warm tanks, the cryogenic gas will almost immediately turn into vapour. LNG for example has a liquid to gas expansion ratio 1: 600. Therefore, to enable the liquid to be loaded into the tank at a reasonable loading rate, the necessity of large compressors are required to remove the vapour generated in the process.
By reducing the cargo tank temperature, the amount of heat that is available to transfer into and heat the LNG is minimized. Consequently the amount of vapour generated can be maintained within reasonable limits.
2. Cargo tank Material
Bofort’s ISO Cryogenic tank containers are constructed of stainless steel which is a material, that retains its flexibility and strength characteristics over the temperature range being considered (-196ºC +50ºC). However problems could occur if the material is subjected to very local and rapid cooling such as when a small droplet of cryogenic gas comes into contact with a warm tank wall. Because of the transfer of the heat from the wall into the liquid, the temperature at the particular point will decrease rapidly causing large thermal stresses to arise between the point and the surrounding material. This could lead to stress cracking. (cold spot)
The pipe-work with the tank is constructed of stainless steel tubes. If subjected to rapid cooling thermal stress within the material can be excessive, leading to the material cracking.
All three reasons are of equal importance as each, if not carefully controlled, can have a significant impact on the tank structure and overall safety of the tank.
ISO Cryogenic tank containers cooling down with liquid LIQUID NITROGEN
After the cargo system has been gassed up the headers and tanks must be cooled down before loading can commence. The cool down operation follows immediately after the completion of gassing up using LIN
The rate of cool down is limited for the following reasons.
To avoid excessive stresses. vapour generated during the cool down of the tank must remain within the capabilities of the compressors, to maintain a tank pressure safely below of the release pressure of the safety valves.
LIN is supplied from the terminal to the cool down line and from there directly to the spray header. The various spray valves are operated in order to produce a temperature profile in line with, but not exceeding, the manufacturers’ instructions. Some tanks may require a minimum temperature before bulk loading may commence; this temperature is to be strictly adhered to.